Selected publications

LOW-DIMENSIONAL AND OTHER CHALCOGENIDES

  • Elena Hajdeu-Chicarosh, Victoria Rotaru, Sergiu Levcenco, Rosalia Serna, Ivan A Victorov, Maxim Guc, Raquel Caballero, José Manuel Merino, Ernest Arushanov, Máximo León

Raman and spectroscopic ellipsometry study of Sb 2 S 3 and Sb 2 Se 3 bulk poly-crystals

Physical Chemistry Chemical Physics 2023

  • Raquel Caballero, Victor Condé, Máximo León

SnS thin films grown by sulfurization of evaporated Sn layers: Effect of sulfurization temperature and pressure

Thin Solid Films 2016, 612, 202-207.

KESTERITE THIN-FILMS AND SOLAR CELLS

  • Andrea Ruiz‐Perona, David Palma‐Lafuente, Yudania Sánchez, Maxim Guc, Tim Kodalle, Mohamed Ould Salem, Marcel Placidi, Rosalia Serna, Alejandro Pérez‐Rodríguez, José Manuel Merino, Raquel Caballero

Semitransparent Wide Bandgap Cu2ZnGe(S,Se)4 Thin‐Film Solar Cells: Role of the Sulfurization Process

Solar RRL 2024, 2300947.

  • David Palma-Lafuente, Pablo Diez-Silva, Victoria Rotaru, Tariq Jawhari, Tobias Bertram, Pablo Reyes-Figueroa, Maxim Guc, José Manuel Merino, Raquel Caballero

Sulfurization of co-evaporated Cu2ZnGeSe4 layers: Influence of the precursor cation’s ratios on the properties of Cu2ZnGe (S, Se) 4 thin films

Solar Energy Materials and Solar Cells 2023, 254, 112243.

  • Elena Hajdeu-Chicarosh, Sergiu Levcenko, Rosalia Serna, Ivan V Bodnar, Ivan A Victorov, Oxana Iaseniuc, Raquel Caballero, José Manuel Merino, Ernest Arushanov, Máximo León

Spectroscopic ellipsometry study of Cu2Zn (GexSi1-x) Se4 bulk poly-crystals

Solid State Sciences 2022, 132, 106982

  • Andrea Ruiz-Perona, Maxim Guc, Yudania Sanchez, Tim Kodalle, Jose M Merino, Maximo Leon, Raquel Caballero

Wide band gap Cu2ZnGe (S, Se) 4 thin films and solar cells: Influence of Na content and incorporation method

Solar Energy 2021, 226, 251-259.

  • Andrea Ruiz-Perona, Galina Gurieva, Michael Sun, Tim Kodalle, Yudania Sánchez, Maarja Grossberg, José Manuel Merino, Susan Schorr, Máximo León, Raquel Caballero

Routes to develop a [S]/([S]+[Se]) gradient in wide band-gap Cu2ZnGe (S, Se) 4 thin-film solar cells

Journal of Alloys and Compounds 2021, 868, 159253.

  • Andrea Ruiz-Perona, Yudania Sánchez, Maxim Guc, Tim Kodalle, Marcel Placidi, José Manuel Merino, Fátima Cabello, Marina García-Pardo, Máximo León, Raquel Caballero

The effect of annealing temperature on Cu2ZnGeSe4 thin films and solar cells grown on transparent substrates

Journal of Physics: Materials 2021, 4, 034009.

  • Sergiu Levcenko, Elena Hajdeu-Chicarosh, Rosalía Serna, Maxim Guc, Ivan A Victorov, Alexandr Nateprov, Ivan V Bodnar, Raquel Caballero, Jose Manuel Merino, Ernest Arushanov, Maximo Leon

Spectroscopic ellipsometry study of Cu2ZnSn (SxSe1-x) 4 bulk polycrystals

Journal of Alloys and Compounds 2020, 843, 156013.

  • Andrea Ruiz-Perona, Yudania Sánchez, Maxim Guc, Samira Khelifi, Tim Kodalle, Marcel Placidi, José Manuel Merino, Máximo León, Raquel Caballero

Effect of Na and the back contact on Cu2Zn (Sn, Ge) Se4 thin-film solar cells: Towards semi-transparent solar cells

Solar Energy 2020, 206, 555-563.

  • IS Babichuk, MO Semenenko, R Caballero, OI Datsenko, S Golovynskyi, Ran Qiu, Chun Huang, Rui Hu, IV Babichuk, RR Ziniuk, M Stetsenko, OA Kapush, Jian Yang, Baikui Li, Junle Qu, M Leon

Raman mapping of MoS2 at Cu2ZnSnS4/Mo interface in thin film

Solar Energy 2020, 205, 154-160.

  • A Ruiz-Perona, Y Sánchez, M Guc, L Calvo-Barrio, T Jawhari, JM Merino, M León, R Caballero

Influence of Zn excess on compositional, structural and vibrational properties of Cu2ZnSn0. 5Ge0. 5Se4 thin films and their effect on solar cell efficiency

Solar Energy 2020, 199, 864-871

  • IS Babichuk, MO Semenenko, S Golovynskyi, R Caballero, OI Datsenko, IV Babichuk, Ji Li, Guiwen Xu, Ran Qiu, Chun Huang, Rui Hu, I Golovynska, V Ganus, Baikui Li, Junle Qu, M Leon

Control of secondary phases and disorder degree in Cu2ZnSnS4 films by sulfurization at varied subatmospheric pressures

Solar Energy Materials and Solar Cells 2019, 200, 109915.

  • Thomas Ratz, Guy Brammertz, Raquel Caballero, Maximo León, Stella Canulescu, Jorgen Schou, L Gütay, D Pareek, T Taskesen, Dae-Hwan Kim, Jin-Kyu Kang, C Malerba, Alex Redinger, E Saucedo, Byungha Shin, H Tampo, K Timmo, ND Nguyen, B Vermang

Physical routes for the synthesis of kesterite

Journal of Physics: Energy 2019,1, 042003.

  • Antonio Cabas‐Vidani, Stefan G Haass, Christian Andres, Raquel Caballero, Renato Figi, Claudia Schreiner, José A Márquez, Charles Hages, Thomas Unold, Davide Bleiner, Ayodhya N Tiwari, Yaroslav E Romanyuk

High‐Efficiency (LixCu1−x)2ZnSn(S,Se)4 Kesterite Solar Cells with Lithium Alloying

Advanced Energy Materials 2018, 8, 1801191

  • Raquel Caballero, Stefan G Haass, C Andres, Laia Arques, Florian Oliva, Victor Izquierdo-Roca, Yaroslav Romanyuk

Effect of Magnesium incorporation on solution-processed kesterite solar cells

Frontiers in Chemistry 2018, 6, 1-9.

  • Christian Andres, Torsten Schwarz, Stefan G Haass, Thomas Paul Weiss, Romain Carron, Raquel Caballero, Renato Figi, Claudia Schreiner, Melanie Bürki, Ayodhya Nath Tiwari, Yaroslav E Romanyuk

Decoupling of optoelectronic properties from morphological changes in sodium treated kesterite thin film solar cells

Solar Energy 2018, 175, 94-100.

  • L De la Cueva, Y Sánchez, L Calvo-Barrio, Florian Oliva, V Izquierdo-Roca, Samira Khelifi, T Bertram, JM Merino, M León, Raquel Caballero

Sulfurization of co-evaporated Cu2ZnSnSe4 thin film solar cells: The role of Na

Solar Energy Materials and Solar Cells 2018, 186, 115-123.

  • Sergiu Levcenko, Elena Hajdeu-Chicarosh, Elena Garcia-Llamas, Raquel Caballero, Rosalía Serna, Ivan V Bodnar, Ivan A Victorov, Maxim Guc, José Manuel Merino, Alejandro Perez-Rodriguez, Ernest Arushanov, Máximo León

Spectroscopic ellipsometry study of Cu2ZnSnS4 bulk poly-crystals

Applied Physics Letters 2018, 112, 161901.

  • E Garcia-Llamas, JM Merino, R Gunder, K Neldner, D Greiner, A Steigert, S Giraldo, V Izquierdo-Roca, E Saucedo, M León, S Schorr, Raquel Caballero

Cu2ZnSnS4 thin film solar cells grown by fast thermal evaporation and thermal treatment

Solar Energy 2017, 141, 236-241.

  • E Garcia-Llamas, M Guc, Ivan V Bodnar, Xavier Fontané, Raquel Caballero, Jose Manuel Merino, Maximo León, Víctor Izquierdo-Roca

Multiwavelength excitation Raman scattering of Cu2ZnSn1-xGex (S, Se) 4 single crystals for earth abundant photovoltaic applications

Journal of Alloys and Compounds 2017, 692, 249-256.

  • Eduard Garcia-Llamas, José Manuel Merino, Rosalía Serna, X Fontané, Ivan A Victorov, Alejandro Pérez-Rodríguez, Máximo León, Ivan V Bodnar, Victor Izquierdo-Roca, Raquel Caballero

Wide band-gap tuning Cu2ZnSn1− xGexS4 single crystals: optical and vibrational properties

Solar Energy Materials and Solar Cells 2016, 158, 147-153.

  • Simón López-Marino, Moises Espíndola-Rodríguez, Y Sánchez, X Alcobé, Florian Oliva, Haibing Xie, Markus Neuschitzer, S Giraldo, Marcel Placidi, Raquel Caballero, Victor Izquierdo-Roca, Alejandro Pérez-Rodríguez, Edgardo Saucedo

The importance of back contact modification in Cu2ZnSnSe4 solar cells: The role of a thin MoO2 layer

Nano Energy 2016, 26, 708-721.

  • Raquel Caballero, José María Cano-Torres, Elena Garcia-Llamas, X Fontané, Alejandro Pérez-Rodríguez, D Greiner, CA Kaufmann, José Manuel Merino, I Victorov, G Baraldi, M Valakh, I Bodnar, Victor Izquierdo-Roca, Máximo León

Towards the growth of Cu2ZnSn1− xGexS4 thin films by a single-stage process: Effect of substrate temperature and composition

Solar Energy Materials and Solar Cells 2015, 139, 1-9.

  • R Caballero, I Victorov, R Serna, JM Cano-Torres, C Maffiotte, E Garcia-Llamas, JM Merino, M Valakh, I Bodnar, M León

Band-gap engineering of Cu2ZnSn1-x GexS4 single crystals and influence of the surface properties

Acta Materialia 2014, 79, 181-187.

  • Máximo León, Sergiu Levcenko, Rosalía Serna, Ivan V Bodnar, Alexander Nateprov, Maxim Guc, Galina Gurieva, Nair López, José Manuel Merino, Raquel Caballero, S Schorr, Alejandro Perez-Rodriguez, Ernest Arushanov

Spectroscopic ellipsometry study of Cu2ZnSnSe4 bulk crystals

Applied Physics Letters 2014, 105, 061909.

  • M Guc, Raquel Caballero, KG Lisunov, N López, E Arushanov, JM Merino, M León

Disorder and variable-range hopping conductivity in Cu2ZnSnS4 thin films prepared by flash evaporation and post-thermal treatment

Journal of Alloys and Compounds 2014, 596, 140-144.

  • Raquel Caballero, E Garcia-Llamas, JM Merino, M León, I Babichuk, V Dzhagan, V Strelchuk, M Valakh

Non-stoichiometry effect and disorder in Cu2ZnSnS4 thin films obtained by flash evaporation: Raman scattering investigation

Acta Materialia 2014, 65, 412-417.

CHALCOPYRITE (CIGS) THIN-FILM SOLAR CELLS

  • R Caballero, M Nichterwitz, A Steigert, A Eicke, I Lauermann, HW Schock, CA Kaufmann

Impact of Na on MoSe2 formation at the CIGSe/Mo interface in thin-film solar cells on polyimide foil at low process temperatures

Acta Materialia 2014, 63, 54-62.

  • Harry Mönig, David Lockhorn, Nabi Aghdassi, Alexander Timmer, Christian A Kaufmann, Raquel Caballero, Helmut Zacharias, Harald Fuchs

Heat Induced Passivation of CuInSe2 Surfaces: A Strategy to Optimize the Efficiency of Chalcopyrite Thin Film Solar Cells?

Advanced Materials Interfaces 2014, 1, 1300040.

  • H Rodriguez-Alvarez, R Mainz, R Caballero, D Abou-Ras, M Klaus, S Gledhill, A Weber, CA Kaufmann, H-W Schock

Real-time study of Ga diffusion processes during the formation of Cu (In, Ga) Se2: The role of Cu and Na content

Solar Energy Materials and Solar Cells 2013, 116, 102-109.

  • Melanie Nichterwitz, Raquel Caballero, Christian A Kaufmann, Hans-Werner Schock, Thomas Unold

Generation-dependent charge carrier transport in Cu (In, Ga) Se2/CdS/ZnO thin-film solar-cells

Journal of Applied Physics 2013, 113, 044515.

  • R Caballero, CA Kaufmann, V Efimova, T Rissom, V Hoffmann, HW Schock

Investigation of Cu(In,Ga)Se2 thin‐film formation during the multi‐stage co‐evaporation process

Progress in Photovoltaics: Research and Applications 2013, 21, 30-46.

  • Tobias Eisenbarth, Raquel Caballero, Christian A Kaufmann, Axel Eicke, Thomas Unold

Influence of iron on defect concentrations and device performance for Cu(In,Ga)Se2 solar cells on stainless steel substrates

Progress in Photovoltaics: Research and Applications 2012, 20, 568-574.

  • Daniel Abou‐Ras, Sebastian S Schmidt, Raquel Caballero, Thomas Unold, Hans‐Werner Schock, Christoph T Koch, Bernhard Schaffer, Miroslava Schaffer, Pyuck‐Pa Choi, Oana Cojocaru‐Mirédin

Confined and chemically flexible grain boundaries in polycrystalline compound semiconductors

Advanced Energy Materials 2012, 2, 992-998.

  • Daniel Abou-Ras, Bernhard Schaffer, Miroslava Schaffer, Sebastian S Schmidt, Raquel Caballero, Thomas Unold

Direct insight into grain boundary reconstruction in polycrystalline Cu (In, Ga) Se 2 with atomic resolution

Physical Review Letters 2012, 108, 075502.

  • Raquel Caballero, Christian A Kaufmann, Tobias Eisenbarth, Thomas Unold, Reiner Klenk, Hans‐Werner Schock

High efficiency low temperature grown Cu(In,Ga)Se2 thin film solar cells on flexible substrates using NaF precursor layers

Progress in Photovoltaics: Research and Applications 2011, 19, 547-551.

  • Harry Mönig, Y Smith, Raquel Caballero, CA Kaufmann, Iver Lauermann, M Ch Lux-Steiner, S Sadewasser

Direct Evidence for a Reduced Density of Deep Level Defects at Grain Boundaries of Cu(In,Ga)Se2 Thin Films

Physical Review Letters 2010, 105, 116802.

  • Raquel Caballero, Víctor Izquierdo-Roca, Xavier Fontané, Christian A Kaufmann, J Álvarez-García, Axel Eicke, Lorenzo Calvo-Barrio, Alejandro Pérez-Rodríguez, Hans-Werner Schock, Joan Ramón Morante

Cu deficiency in multi-stage co-evaporated Cu (In, Ga) Se2 for solar cells applications: Microstructure and Ga in-depth alloying

Acta Materialia 2010, 58, 3468-3476.

  • R Caballero, CA Kaufmann, T Eisenbarth, A Grimm, I Lauermann, T Unold, R Klenk, HW Schock

Influence of Na on Cu (In, Ga) Se2 solar cells grown on polyimide substrates at low temperature: Impact on the Cu (In, Ga)Se2/Mo interface

Applied Physics Letters 2010, 96, 092104.

  • Tobias Eisenbarth, Thomas Unold, Raquel Caballero, Christian A Kaufmann, Hans-Werner Schock

Interpretation of admittance, capacitance-voltage, and current-voltage signatures in Cu (In, Ga) Se2 thin film solar cells

Journal of Applied Physics 2010, 107, 034509.

  • CA Kaufmann, R Caballero, T Unold, R Hesse, R Klenk, S Schorr, M Nichterwitz, H-W Schock

Depth profiling of Cu (In, Ga) Se2 thin films grown at low temperatures

Solar Energy Materials and Solar Cells 2009, 93, 859-863.

  • R Caballero, CA Kaufmann, T Eisenbarth, M Cancela, R Hesse, T Unold, A Eicke, R Klenk, HW Schock

The influence of Na on low temperature growth of CIGS thin film solar cells on polyimide substrates

Thin Solid Films 2009, 517, 2187-2190.

  • R Caballero, C Guillén, MT Gutiérrez, CA Kaufmann

CuIn1−xGaxSe2‐based thin‐film solar cells by the selenization of sequentially evaporated metallic layers

Progress in Photovoltaics: Research and Applications 2006, 14, 145-153.

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